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Author(s):   Blackmore, D.R.; Hinshelwood, C.
Title:   Derivation of rate constants for steps in the free-radical chain decomposition of paraffins
Journal:   Proc. R. Soc. London A
Volume:   268
Year:   1962
Reference type:   Journal article
Squib:   1962BLA/HIN36

Reaction:   1-C8H171-C7H14 + ·CH3
Reaction order:   1
Temperature:   763 - 783 K
Rate expression:   3.16x1016 [s-1] e-197884 [J/mole]/RT
Category:  Theory
Data type:   Ab initio

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
763 8.97E2
775 1.45E3
783 1.99E3