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Author(s):   Dijkstra, A.J.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   Reactions of difluoroamino-radicals. Part III. Addition to olefins
Journal:   J. Chem. Soc. A
Page(s):  
Year:   1967
Reference type:   Journal article
Squib:   1967DIJ/KER105

Reaction:   CH3CHCH2NF2CH3CH=CH2 + NF2
Reaction order:   1
Reference reaction:   NF2 + CH3CHCH2NF2Propane, 1,2-(difluoroamino)-
Reference reaction order:   2
Temperature:   334 - 428 K
Rate expression:   6.02x1020 [molecule/cm3] e-56455 [J/mole]/RT
Bath gas:   N2F4
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
334 8.93E11
350 2.26E12
375 8.24E12
400 2.56E13
425 6.94E13
428 7.76E13