Author(s):   Sellevag, S.R.; Nyman, G.; Nielsen, C.J.
Title:   Study of the carbon-13 and deuterium kinetic isotope effects in the Cl and OH reactions of CH4 and CH3Cl
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   141 - 152
Year:   2006
Reference type:   Journal article
Squib:   2006SEL/NYM141-152

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
2006SEL/NYM141-152	CH₃Cl + ·OH → ·CH₂Cl + H₂O	298	1.41	1.41	2
Reference reaction: ·OH + CH₂DCl → Products				2
2006SEL/NYM141-152	CH₃Cl + ·OH → ·CH₂Cl + H₂O	298	2.03	2.03	2
Reference reaction: ·OH + CHD₂Cl → Products				2
2006SEL/NYM141-152	CH₃Cl + ·Cl → ·CH₂Cl + HCl	298	2.27	2.27	2
Reference reaction: CHD₂Cl + ·Cl → Products				2
2006SEL/NYM141-152	CH₃Cl + ·Cl → ·CH₂Cl + HCl	298	1.42	1.42	2
Reference reaction: CH₂DCl + ·Cl → Products				2
2006SEL/NYM141-152	[13]CH₄ + ·Cl → [13]CH₃ + HCl	200 - 1500		0.00E00	2
Reference reaction: [12]CH₄ + ·Cl → [12]CH₃ + HCl				2
2006SEL/NYM141-152	[13]CH₄ + ·OH → [13]CH₃ + H₂O	200 - 1500		0.00E00	2
Reference reaction: [12]CH₄ + ·OH → [12]CH₃ + H₂O				2
2006SEL/NYM141-152	[13]CH₃Cl + ·OH → [13]CH₂Cl + H₂O	200 - 1500		0.00E00	2
Reference reaction: [12]CH₃Cl + ·OH → [12]CH₂Cl + H₂O				2
2006SEL/NYM141-152	[13]CH₃Cl + ·Cl → [13]CH₂Cl + HCl	200 - 1500		0.00E00	2
Reference reaction: [12]CH₃Cl + ·Cl → [12]CH₂Cl + HCl				2
2006SEL/NYM141-152	CD₄ + ·Cl → CD₃ + HCl	200 - 1500		0.00E00	2
Reference reaction: CH₄ + ·Cl → ·CH₃ + HCl				2
2006SEL/NYM141-152	CD₄ + ·OH → CD₃ + HDO	200 - 1500		0.00E00	2
Reference reaction: CH₄ + ·OH → ·CH₃ + H₂O				2
2006SEL/NYM141-152	CHD₃ + ·OH → Products	200 - 1500		0.00E00	2
Reference reaction: CH₄ + ·OH → ·CH₃ + H₂O				2
2006SEL/NYM141-152	CH₂D₂ + ·OH → Products	200 - 1500		0.00E00	2
Reference reaction: CH₄ + ·OH → ·CH₃ + H₂O				2
2006SEL/NYM141-152	CH₃D + ·OH → Products	200 - 1500		0.00E00	2
Reference reaction: CH₄ + ·OH → ·CH₃ + H₂O				2
2006SEL/NYM141-152	CH₃D + ·Cl → Products	200 - 1500		0.00E00	2
Reference reaction: CH₄ + ·Cl → ·CH₃ + HCl				2
2006SEL/NYM141-152	CH₂D₂ + ·Cl → Products	200 - 1500		0.00E00	2
Reference reaction: CH₄ + ·Cl → ·CH₃ + HCl				2
2006SEL/NYM141-152	CHD₃ + ·Cl → Products	200 - 1500		0.00E00	2
Reference reaction: CH₄ + ·Cl → ·CH₃ + HCl				2
2006SEL/NYM141-152	CD₃Cl + ·Cl → DCl + CD₂Cl	200 - 1500		0.00E00	2
Reference reaction: CH₃Cl + ·Cl → ·CH₂Cl + HCl				2
2006SEL/NYM141-152	CD₃Cl + ·OH → HDO + CD₂Cl	200 - 1500		0.00E00	2
Reference reaction: CH₃Cl + ·OH → ·CH₂Cl + H₂O				2
2006SEL/NYM141-152	·OH + CHD₂Cl → Products	200 - 1500		0.00E00	2
Reference reaction: CH₃Cl + ·OH → ·CH₂Cl + H₂O				2
2006SEL/NYM141-152	·OH + CH₂DCl → Products	200 - 1500		0.00E00	2
Reference reaction: CH₃Cl + ·OH → ·CH₂Cl + H₂O				2
2006SEL/NYM141-152	CH₂DCl + ·Cl → Products	200 - 1500		0.00E00	2
Reference reaction: CH₃Cl + ·Cl → ·CH₂Cl + HCl				2
2006SEL/NYM141-152	CHD₂Cl + ·Cl → Products	200 - 1500		0.00E00	2
Reference reaction: CH₃Cl + ·Cl → ·CH₂Cl + HCl				2

Search returned 22 records.