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Title: Crossed Molecular Beams and Theoretical Studies of the O(P-3)+1,2-Butadiene Reaction: Dominant Formation of Propene plus CO and Ethylidene plus Ketene Molecular Channels
Journal: Chin. J. Chem. Phys.
Volume: 32
Page(s): 113 - 122
Year: 2019
Reference type: Journal article
Squib: 2019CAR/VAN113-122
Reaction:
1,2-butadiene + O· → Products
Reaction order:
2
Rate expression:
no rate data available
Category: Experiment
Data type:
Mechanistic information only
Pressure dependence:
None reported
Experimental procedure:
Molecular beam
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
Comments:
The reaction was studied in crossed-molecular-beam experiments with soft ionization mass-spectrometric detection of products. Product branching fractions and angular distributions were obtained for the atomic oxygen beam peak velocity of 2470 m/s. No thermal values were obtained.
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