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Author(s):   Caracciolo, A.; Vanuzzo, G.; Balucani, N.; Stranges, D.; Tanteri, S.; Cavallotti, C.; Casavecchia, P.
Title:   Crossed Molecular Beams and Theoretical Studies of the O(P-3)+1,2-Butadiene Reaction: Dominant Formation of Propene plus CO and Ethylidene plus Ketene Molecular Channels
Journal:   Chin. J. Chem. Phys.
Volume:   32
Page(s):   113 - 122
Year:   2019
Reference type:   Journal article
Squib:   2019CAR/VAN113-122

Reaction:   1,2-butadiene + → Products
Reaction order:   2
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Pressure dependence:   None reported
Experimental procedure:   Molecular beam
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The reaction was studied in crossed-molecular-beam experiments with soft ionization mass-spectrometric detection of products. Product branching fractions and angular distributions were obtained for the atomic oxygen beam peak velocity of 2470 m/s. No thermal values were obtained.

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