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Author(s):   Jones, Y.; Holmes, B.E.; Duke, D.W.; Tipton, D.L.
Title:   Threshold energies and substituent effects for unimolecular elimination of HCl (DCl) and HF (DF) from chemically activated CF2ClCH3 and CF2ClCD3
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   94
Page(s):   4957 - 4963
Year:   1990
Reference type:   Journal article
Squib:   1990JON/HOL4957-4963

Reaction:   ·CClF2 + ·CClF2CF2Cl2 + ·CF2
Reaction order:   2
Reference reaction:   ·CClF2 + ·CClF2CF2Cl-CF2Cl
Reference reaction order:   2
Temperature:   298 K
Rate expression:   1.7x10-1±4.9x10-2
Bath gas:   SF6
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

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