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Accessibility information
Author(s):   Abell, P.I.
Title:   Relative reactivity of olefins to HBr in the gas phase
Journal:   Trans. Faraday Soc.
Volume:   60
Page(s):   2214 - 2223
Year:   1964
Reference type:   Journal article
Squib:   1964ABE2214-2223

Reaction:   CH2=CHBr + HBrCH2BrCH2Br
Reaction order:   2
Reference reaction:   C2H4 + HBrC2H5Br
Reference reaction order:   2
Temperature:   313 - 393 K
Pressure:  2.00E-2 - 8.00E-2 bar
Rate expression:   3.4x10-1 e1788 [J/mole]/RT
Bath gas:   HBr
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
313 6.76E-1
325 6.59E-1
350 6.28E-1
375 6.03E-1
393 5.88E-1