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Author(s):   Bejan, I.; Schurmann, A.; Barnes, I.; Benter, T.
Title:   Kinetics of the gas-phase reactions of OH radicals with a series of trimethylphenols
Journal:   Int. J. Chem. Kinet.
Volume:   44
Page(s):   117 - 124
Year:   2012
Reference type:   Journal article
Squib:   2012BEJ/SCH117-124

Reaction:   Phenol, 2,4,5-trimethyl- + ·OH → Products
Reaction order:   2
Reference reaction:   CH2=C(CH3)CH=CH2 + ·OH → Products
Temperature:   298 K
Pressure:  1.33E-3 bar
Rate expression:   1.17x10-10 [±2.4x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   The quoted error includes the 2σ statistical error obtained from the linear regression analysys plus a 20% contribution to cover possible errors in the recommended value of the rate coefficient for reference compound with OH, and also the errors arising from the IR spectral subtraction procedure.

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