Author(s):   Sawrey, B.A.; O'Neal, H.E.; Ring, M.A.; Coffey, D., Jr.
Title:   The gas-phase decomposition of methylsilane. Part I. Mechanism of decomposition under shock-tube conditions
Journal:   Int. J. Chem. Kinet.
Volume:   16
Page(s):   7 - 21
Year:   1984
Reference type:   Journal article
Squib:   1984SAW/ONE7-21

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
1984SAW/ONE7-21	CH₃SiH₃ → Other Products + H₂	1120 - 1250	0.91		1
Reference reaction: CH₃SiH₃ → Products				1
1984SAW/ONE7-21	CH₃SiH₃ → CH₄ + SiH₂	1120 - 1250	0.09		1
Reference reaction: CH₃SiH₃ → Products				1
1984SAW/ONE7-21	CH₃SiD₃ → CH₃D + :SiD₂	1120 - 1250	0.15		1
Reference reaction: CH₃SiD₃ → Products				1
1984SAW/ONE7-21	CH₃SiD₃ → D₂ + CH₃DSi:	1120 - 1250	0.71		1
Reference reaction: CH₃SiD₃ → Products				1
1984SAW/ONE7-21	CH₃SiD₃ → HD + CH₂=SiD₂	1120 - 1250	0.14		1
Reference reaction: CH₃SiD₃ → Products				1

Search returned 5 records.