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Accessibility information
Author(s):   Christiansen, C.J.; Francisco, J.S.
Title:   Atmospheric Oxidation Mechanism of 1,2-Dibromoethane
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   7189 - 7204
Year:   2009
Reference type:   Journal article
Squib:   2009CHR/FRA7189-7204

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2009CHR/FRA7189-7204   CH2BrCH2Br + ·OH → CH2BrCH(·)Br + H2O                     2
    2009CHR/FRA7189-7204   CH2BrCHBrO· → Br· + Acetaldehyde, bromo-                     1
    2009CHR/FRA7189-7204   ·OH + Acetaldehyde, bromo- → ·CHBrCHO + H2O                     2
    2009CHR/FRA7189-7204   CHBr(OO·)CHO → HOOCHBrC(·)=O                     1
    2009CHR/FRA7189-7204   CHBrO(·)CHO + O2 → CBr(O)CH(O) + HO2                     2
    2009CHR/FRA7189-7204   CBr(O)CH(O) + ·OH → BrC(O)C(O)· + H2O                     2
    2009CHR/FRA7189-7204   CHBr(OO·)CHO → HOOC(·)Br-CHO                     1
    2009CHR/FRA7189-7204   HC(O)CO → CO + HCO                     1
    2009CHR/FRA7189-7204   HOOC(·)Br-CHO → CBr(O)CH(O) + ·OH                     1
    2009CHR/FRA7189-7204   CH2BrCHBrO· → Br· + Acetaldehyde, bromo-                     1
    2009CHR/FRA7189-7204   ·OH + Acetaldehyde, bromo- → BrCH2C(O)(.) + H2O                     2
    2009CHR/FRA7189-7204   CH2BrC(O)O· → CO2 + ·CH2Br                     1
    2009CHR/FRA7189-7204   CH2BrO → CH2O + Br·                     1
    2009CHR/FRA7189-7204   CH2BrO + O2HO2 + HC(O)Br                     2
    2009CHR/FRA7189-7204   BrCH2C(O)(.) → CO + ·CH2Br                     1
    2009CHR/FRA7189-7204   CH2BrCHBrO· → HC(O)Br + ·CH2Br                     1
    2009CHR/FRA7189-7204   CH2BrCHBrO· + O2CH2BrC(O)Br + HO2                     2
    2009CHR/FRA7189-7204   CH2BrC(O)Br + ·OH → ·CHBrCBrO + H2O                     2
    2009CHR/FRA7189-7204   CHBrO(·)COBr + O2H2O + BrCOCOBr                     2
    2009CHR/FRA7189-7204   CHBrO(·)COBr → CBr(O)CH(O) + Br·                     1

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