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Accessibility information
Author(s):   Wu, J.; Khaled, F.; Ning, H.; Ma, L.; Farooq, A.; Ren, W.
Title:   Theoretical and Shock Tube Study of the Rate Constants for Hydrogen Abstraction Reactions of Ethyl Formate
Journal:   J. Phys. Chem. A
Volume:   121
Page(s):   6304 - 6313
Year:   2017
Reference type:   Journal article
Squib:   2017WU/KHA6304-6313

Reaction:   HC(O)OC2H5 + ·OH → Products
Reaction order:   2
Temperature:   900 - 1321 K
Pressure:  1.42 - 2.03 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Rate constants were determined for a range of temperatures; however, no Arrhenius expression is given for the k(T) dependence. Instead, rate constants for individual temperatures are presented in a tabular format. Experimental results are in agreement with the computational k(T) dependence obtained in the same article.

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