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Author(s):   Orlando, J.J.; Tyndall, G.S.
Title:   Oxidation Mechanisms for Ethyl Chloride and Ethyl Bromide under Atmospheric Conditions
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   312 - 319
Year:   2002
Reference type:   Journal article
Squib:   2002ORL/TYN312-319

Reaction:   C2H5Cl + ·ClHCl + CH2CH2Cl
Reaction order:   2
Reference reaction:   C2H5Cl + ·Cl → Products
Reference reaction order:   2
Temperature:   220 - 298 K
Pressure:  0.95 bar
Rate expression:   1.18 e-4714 [J/mole]/RT
Rate constant is a lower limit.
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Rate constants were fit to Arrhenius expression by abstracter. Reported rate constants were measured in varying mixtures of N2 and O2. No dependence on bath gas composition was observed.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
220 8.97E-2
225 9.49E-2
250 1.22E-1
275 1.50E-1
298 1.76E-1