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Accessibility information
Author(s):   Wakamatsu, H.; Hidaka, Y.
Title:   Shock-tube and modeling study of chloroethane pyrolysis and oxidation
Journal:   Int. J. Chem. Kinet.
Volume:   40
Page(s):   320 - 339
Year:   2008
Reference type:   Journal article
Squib:   2008WAK/HID320-339

Reaction:   C2H5Cl + ·ClHCl + CH2CH2Cl
Reaction order:   2
Temperature:   900 - 1650 K
Pressure:  0.81 - 3.24 bar
Rate expression:   5.71x10-12 [cm3/molecule s] e-4351 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Other (direct)
Comments:   The shock tube was a standard-type connected to laser absorption, IR-emission, gas chromatograph and UV absorption equipments.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
900 3.19E-12
950 3.29E-12
1000 3.38E-12
1050 3.47E-12
1100 3.55E-12
1150 3.62E-12
1200 3.69E-12
1250 3.76E-12
1300 3.82E-12
1350 3.88E-12
1400 3.93E-12
1450 3.98E-12
1500 4.03E-12
1550 4.08E-12
1600 4.12E-12
1650 4.16E-12