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Author(s):   Stimson, V.R.; Watson, E.J.
Title:   Catalysis by hydrogen halides in the gas phase. IX. Tertiary butyl ethyl ether and hydrogen bromide
Journal:   Aust. J. Chem.
Volume:   19
Page(s):   75 - 84
Year:   1966
Reference type:   Journal article
Squib:   1966STI/WAT75-84

Reaction:   tert-C4H9OC2H5CH3CHO + iso-C4H10
Reaction order:   1
Temperature:   536 - 610 K
Pressure:  5.33E-2 - 0.40 bar
Rate expression:   5.11x1010 [s-1] e-167121 [J/mole]/RT
Bath gas:   HBr
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
536 2.64E-6
550 6.87E-6
575 3.37E-5
600 1.44E-4
610 2.50E-4