 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Methyl radical reactions with isopropanol and methanol, their ethers and their deuterated derivatives
Journal: Trans. Faraday Soc.
Volume: 64
Page(s):
Year: 1968
Reference type: Journal article
Squib: 1968GRA/HER2723
Reaction:
CD3 + iso-C3H7CHOD → Other Products + CHD3
Reaction order:
2
Reference reaction:
CD3 + CD3 → C2D6
Temperature:
408 - 523
K
Rate expression:
2.46x10-13 [cm3/molecule s] e-33092 [±661 J/mole]/RT
Uncertainty:
1.2300000190734863
Bath gas:
(CD3)2CO
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 408 | 1.43E-17 |
| 425 | 2.11E-17 |
| 450 | 3.54E-17 |
| 475 | 5.64E-17 |
| 500 | 8.58E-17 |
| 523 | 1.22E-16 |