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Author(s):   Gray, P.; Herod, A.A.
Title:   Methyl radical reactions with isopropanol and methanol, their ethers and their deuterated derivatives
Journal:   Trans. Faraday Soc.
Volume:   64
Year:   1968
Reference type:   Journal article
Squib:   1968GRA/HER2723

Reaction:   CD3 + iso-C3H7CHOD → Other Products + CHD3
Reaction order:   2
Reference reaction:   CD3 + CD3C2D6
Temperature:   408 - 523 K
Rate expression:   2.46x10-13 [cm3/molecule s] e-33092 [±661 J/mole]/RT
Uncertainty:   1.2300000190734863
Bath gas:   (CD3)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
408 1.43E-17
425 2.11E-17
450 3.54E-17
475 5.64E-17
500 8.58E-17
523 1.22E-16