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Author(s):   Vasini, E.J.; Schumacher, H.J.
Title:   Die kinetik der thermischen bildung von chlorfluorsulfonat, FSO3Cl, aus Bis-fluorsulfurylperoxid und chlor
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   65
Page(s):   238 - 247
Year:   1969
Reference type:   Journal article
Squib:   1969VAS/SCH238-247

Reaction:   FSO2OCl + ·ClCl2 + FSO3
Reaction order:   2
Reference reaction:   FSO3 + ·Cl → FSO2OCl
Reference reaction order:   2
Temperature:   372 - 409 K
Pressure:  6.67E-2 - 0.40 bar
Rate expression:   4.28x101 e-13636 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
372 5.21E-1
375 5.40E-1
400 7.09E-1
409 7.76E-1