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Author(s):   Croce de Cobos, A.E.; Cobos, C.J.; Castellano, E.
Title:   Pulsed laser photolysis study of the reaction Cl+FSO3+M→’FSO2OCl+M
Journal:   Chem. Phys. Lett.
Volume:   158
Page(s):   157 - 160
Year:   1989
Reference type:   Journal article
Squib:   1989CRO/COB157-160

Reaction:   FSO2OCl + ·ClCl2 + FSO3
Reaction order:   2
Temperature:   297 K
Pressure:  3.20E-2 - 0.94 bar
Rate expression:   1.3x10-11 [±1.99x10-12 cm3/molecule s]
Bath gas:   CF4
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

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