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Accessibility information
Author(s):   Clark, T.C.; Clyne, M.A.A.
Title:   The nitric oxide-catalyzed recombination of chlorine atoms
Journal:   Chem. Commun.
Page(s):   287 - 289
Year:   1966
Reference type:   Journal article
Squib:   1966CLA/CLY287-289

Reaction:   NO + ·ClNOCl
Reaction order:   3
Temperature:   270 - 620 K
Pressure:  9.33E-4 - 2.67E-3 bar
Rate expression:   1.21x10-32 [cm6/molecule2 s] e4598 [±414 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Vis-UV emission

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
270 9.36E-32
275 9.02E-32
300 7.63E-32
325 6.62E-32
350 5.86E-32
375 5.28E-32
400 4.81E-32
425 4.44E-32
450 4.13E-32
475 3.87E-32
500 3.65E-32
525 3.46E-32
550 3.30E-32
575 3.16E-32
600 3.04E-32
620 2.95E-32