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Author(s):   Michael, J.V.; Lee, J.H.
Title:   Rate Constant Measurements at Constant Temperature by the Flash Photolysis-Resonance Fluorescence Technique and Recombination-Dissociation Theory for NO2 and NOCl
Journal:   J. Phys. Chem.
Volume:   83
Year:   1979
Reference type:   Journal article
Squib:   1979MIC/LEE10

Reaction:   NO + ·ClNOCl
Reaction order:   3
Temperature:   200 - 400 K
Pressure:  1.33E-2 - 0.16 bar
Rate expression:   1.18x10-32 [cm6/molecule2 s] e4423 [±177 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
200 1.69E-31
225 1.26E-31
250 9.93E-32
275 8.19E-32
300 6.97E-32
325 6.08E-32
350 5.41E-32
375 4.89E-32
400 4.47E-32