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 Author(s):   Blauer, J.A.; McMath, H.G.; Jaye, F.C.
Title:   The thermal dissociation of chlorine trifluoride behind incident shock waves
Journal:   J. Phys. Chem.
Volume:   73
Page(s):  
Year:   1969
Reference type:   Journal article
Squib:   1969BLA/MCM2683

Reaction:   ClF2 → ClF + ·F
Reaction order:   2
Temperature:   800 - 1300 K
Pressure:  23.33 - 27.73 bar
Rate expression:   1.66x10-10 [cm3/molecule s] e-96448 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
800 8.37E-17
850 1.97E-16
900 4.19E-16
950 8.27E-16
1000 1.52E-15
1050 2.64E-15
1100 4.37E-15
1150 6.91E-15
1200 1.05E-14
1250 1.55E-14
1300 2.21E-14