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Author(s):   Wallington, T.J.; Hurley, M.D.; Maricq, M.M.
Title:   FTIR product study of the self-reaction of FC(O)O2 radicals
Journal:   Chem. Phys. Lett.
Volume:   205
Page(s):   62 - 68
Year:   1993
Reference type:   Journal article
Squib:   1993WAL/HUR62-68

Reaction:   FC(O)O·CO2 + ·F
Reaction order:   1
Reference reaction:   FC(O)O· + FC(O)O· → FC(O)OO(O)CF
Reference reaction order:   2
Temperature:   298 K
Pressure:  0.93 bar
Rate expression:   1.57x1023 [±7.23x1022 molecule/cm3]
Rate constant is a lower limit.
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Fourier transform (FTIR)

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