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Author(s):   Dohmaru, T.; Nagata, Y.
Title:   Kinetics of the gas-phase addition reactions of trichlorosilyl radicals. Part 3.-Additions to 2-olefins
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   78
Page(s):  
Year:   1982
Reference type:   Journal article
Squib:   1982DOH/NAG1141

Reaction:   Cyclopentene + ·CCl3 → Adduct
Reaction order:   2
Reference reaction:   Acetone + ·CCl3 → Adduct
Reference reaction order:   2
Temperature:   406 - 489 K
Rate expression:   1.6x10-1 e10643 [±1272 J/mole]/RT
Uncertainty:   1.40999997
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
406 3.74E0
425 3.25E0
450 2.75E0
475 2.37E0
489 2.19E0