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Author(s):   Stuckey, W.K.; Heicklen, J.
Title:   Some reactions of oxygen atoms. III. Cyclopropane, cyclobutane, cyclopentane, and cyclohexane
Journal:   J. Chem. Phys.
Volume:   46
Page(s):   4843 - 4846
Year:   1967
Reference type:   Journal article
Squib:   1967STU/HEI4843-4846

Reaction:   Cyclobutane + ·OH + Cyclobutyl
Reaction order:   2
Reference reaction:   CF3CF=CF2 + → Products
Temperature:   298 - 398 K
Pressure:  0.67 bar
Rate expression:   5.15x10-13 [cm3/molecule s] e-15881 [J/mole]/RT
Bath gas:   N2O
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Sensitized photolysis
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 8.47E-16
300 8.84E-16
325 1.44E-15
350 2.20E-15
375 3.16E-15
398 4.24E-15