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Title: The thermal decomposition of hexafluoroazomethane
Journal: Can. J. Chem.
Volume: 40
Page(s): 930 - 934
Year: 1962
Reference type: Journal article
Squib: 1962LEV/SIM930-934
Reaction:
(CF3N)2 → ·CF3 + ·CF3 + N2
Reaction order:
1
Temperature:
572 - 634
K
Pressure: 4.00E-4 - 9.73E-2 bar
Rate expression:
1.48x1016 [s-1] e-231142 [±2311 J/mole]/RT
Uncertainty:
1.409999966621399
Bath gas:
(CF3N)2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 572 | 1.16E-5 |
| 575 | 1.49E-5 |
| 600 | 1.12E-4 |
| 625 | 7.13E-4 |
| 634 | 1.34E-3 |