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Author(s):   McGee, T.H.; Waring, C.E.
Title:   The kinetics of the thermal decomposition of hexafluoroazomethane and the reaction of CF3 radicals with methyl ethyl ketone
Journal:   J. Phys. Chem.
Volume:   73
Year:   1969
Reference type:   Journal article
Squib:   1969MCG/WAR2838

Reaction:   (CF3N)2·CF3 + ·CF3 + N2
Reaction order:   1
Temperature:   601 - 651 K
Pressure:  7.68E-2 bar
Rate expression:   2.1x1015 [s-1] e-221165 [J/mole]/RT
Bath gas:   C2H5COCH3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
601 1.26E-4
625 6.90E-4
650 3.54E-3
651 3.77E-3