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Title: The kinetics of the thermal decomposition of hexafluoroazomethane and the reaction of CF3 radicals with methyl ethyl ketone
Journal: J. Phys. Chem.
Volume: 73
Page(s):
Year: 1969
Reference type: Journal article
Squib: 1969MCG/WAR2838
Reaction:
(CF3N)2 → ·CF3 + ·CF3 + N2
Reaction order:
1
Temperature:
601 - 651
K
Pressure: 7.68E-2 bar
Rate expression:
2.1x1015 [s-1] e-221165 [J/mole]/RT
Bath gas:
C2H5COCH3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 601 | 1.26E-4 |
| 625 | 6.90E-4 |
| 650 | 3.54E-3 |
| 651 | 3.77E-3 |