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Author(s):   Rossi, M.; Golden, D.M.
Title:   Rate of decomposition of hexafluoroazomethane and the absolute rate of recombination of trifluoromethyl radical at higher temperatures
Journal:   Int. J. Chem. Kinet.
Volume:   11
Page(s):  
Year:   1979
Reference type:   Journal article
Squib:   1979ROS/GOL775

Reaction:   (CF3N)2·CF3 + ·CF3 + N2
Reaction order:   1
Temperature:   720 - 1050 K
Rate expression:   1.58x1016 [s-1] e-231142 [J/mole]/RT
Bath gas:   (CF3N)2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
720 2.69E-1
725 3.51E-1
750 1.26E0
775 4.17E0
800 1.28E1
825 3.67E1
850 9.88E1
875 2.51E2
900 6.08E2
925 1.40E3
950 3.09E3
975 6.54E3
1000 1.33E4
1025 2.63E4
1050 5.01E4