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Title: Rate of decomposition of hexafluoroazomethane and the absolute rate of recombination of trifluoromethyl radical at higher temperatures
Journal: Int. J. Chem. Kinet.
Volume: 11
Page(s):
Year: 1979
Reference type: Journal article
Squib: 1979ROS/GOL775
Reaction:
(CF3N)2 → ·CF3 + ·CF3 + N2
Reaction order:
1
Temperature:
720 - 1050
K
Rate expression:
1.58x1016 [s-1] e-231142 [J/mole]/RT
Bath gas:
(CF3N)2
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 720 | 2.69E-1 |
| 725 | 3.51E-1 |
| 750 | 1.26E0 |
| 775 | 4.17E0 |
| 800 | 1.28E1 |
| 825 | 3.67E1 |
| 850 | 9.88E1 |
| 875 | 2.51E2 |
| 900 | 6.08E2 |
| 925 | 1.40E3 |
| 950 | 3.09E3 |
| 975 | 6.54E3 |
| 1000 | 1.33E4 |
| 1025 | 2.63E4 |
| 1050 | 5.01E4 |