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Author(s):   Madden, L.K.; Moskaleva, L.V.; Kristyan, S.; Lin, M.C.
Title:   Ab initio MO study of the unimolecular decomposition of the phenyl radical
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   6790 - 6797
Year:   1997
Reference type:   Journal article
Squib:   1997MAD/MOS6790-6797

Reaction:   PhenylBenzyne +
Reaction order:   1
Temperature:   700 - 2500 K
Pressure:  1.01 bar
Rate expression:   6.34x1022 [s-1] (T/298 K)-7.72 e-385792 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
700 1.42E-9
800 2.00E-6
900 5.08E-4
1000 3.91E-2
1100 1.27E0
1200 2.18E1
1300 2.30E2
1400 1.66E3
1500 8.90E3
1600 3.74E4
1700 1.29E5
1800 3.78E5
1900 9.66E5
2000 2.21E6
2100 4.57E6
2200 8.71E6
2300 1.55E7
2400 2.58E7
2500 4.08E7