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Author(s):   Balan, R.C.; Rajakumar, B.
Title:   Cl-Atom-Initiated Atmospheric Degradation of Saturated Cyclic Hydrocarbons: Kinetic and Mechanistic Investigation
Journal:   J. Phys. Chem. A
Volume:   123
Page(s):   7361 - 7373
Year:   2019
Reference type:   Journal article
Squib:   2019BAL/RAJ7361-7373

Reaction:   Methylcyclopentane + ·Cl → Products
Reaction order:   2
Temperature:   283 - 363 K
Pressure:  1.01 bar
Rate expression:   5.71x10-12 [±6.6x10-13 cm3/molecule s] e15124 [±5562 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Isoprene and propylene were used as reference compounds.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
283 3.53E-9
300 2.45E-9
325 1.54E-9
350 1.03E-9
363 8.57E-10