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Author(s):   Sprengnether, M.M.; Demerjian, K.L.; Dransfield, T.J.; Clarke, J.S.; Anderson, J.G.; Donahue, N.M.
Title:   Rate Constants of Nine C6-C9 Alkanes with OH from 230 to 379 K: Chemical Tracers for [OH]
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   5030 - 5038
Year:   2009
Reference type:   Journal article
Squib:   2009SPR/DEM5030-5038

Reaction:   Methylcyclohexane + ·OH → Products
Reaction order:   2
Temperature:   230 - 379 K
Pressure:  1.07E-2 - 1.33E-2 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Laser induced fluorescence
Comments:   Rate constants obtained at individual temperatures are reported but no Arrhenius fit is given. Instead, the temperature dependence of the rate constant is represented with a formula that is more complicated than the Arrhenius or the Modified Arrhenius equations.

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