Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Bejan, I.G.; Winiberg, F.A.F.; Mortimer, N.; Medeiros, D.J.; Brumby, C.A.; Orr, S.C.; Kelly, J.; Seakins, P.W.
Title:   Gas-phase rate coefficients for a series of alkyl cyclohexanes with OH radicals and Cl atoms
Journal:   Int. J. Chem. Kinet.
Volume:   50
Page(s):   544 - 555
Year:   2018
Reference type:   Journal article
Squib:   2018BEJ/WIN544-555

Reaction:   Methylcyclohexane + ·OH → Products
Reaction order:   2
Temperature:   293 K
Pressure:  1.00 bar
Rate expression:   9.5x10-12 [±1.3x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Cyclohexane and isopentane were used as reference compounds. FTIR and gas chromatography were used to monitor the decay of hydrocarbons. Uncertainties represent a combination of statistical errors in the relative rate ratio (2𝜎) and the errors in the reference rate coefficients.

View full bibliographic record.