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Accessibility information
Author(s):   Blades, A.T.
Title:   The kinetics of the pyrolysis of ethyl and isopropyl formates and acetates
Journal:   Can. J. Chem.
Volume:   32
Page(s):   366 - 372
Year:   1954
Reference type:   Journal article
Squib:   1954BLA366-372

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1954BLA366-372   CH3COOCH(CH3)2CH3C(O)OH + CH3CH=CH2  714 - 801   1.00E13       1.88E05      1
  1954BLA366-372   HC(O)OC2H5HCOOH + C2H4  810 - 920   2.13E11       1.85E05      1
  1954BLA366-372   CH3C(O)OC2H5CH3C(O)OH + C2H4  782 - 884   3.06E12       2.00E05      1
  1954BLA366-372   HCOOCH(CH3)2HCOOH + CH3CH=CH2  721 - 811   3.80E12       1.84E05      1

Search returned 4 records.