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Accessibility information
Author(s):   Hautecloque, S.
Title:   Reactions des radicaux CCl3 avec des bromoethanes et deuteriobromoethanes
Journal:   C.R. Acad. Sc. Paris
Volume:   280
Year:   1975
Reference type:   Journal article
Squib:   1975HAU701

Reaction:   CH2BrCH2Br + ·CCl3 → Other Products + CHCl3
Reaction order:   2
Reference reaction:   ·CCl3 + ·CCl3CCl3CCl3
Temperature:   511 - 573 K
Rate expression:   1.02x10-1 [cm3/molecule s] e-157144 [J/mole]/RT
Bath gas:   CCl3Br
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
511 8.86E-18
525 2.38E-17
550 1.22E-16
573 4.85E-16