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Author(s):   Kirk, A.D.; Knox, J.H.
Title:   The pyrolysis of alkyl hydroperoxides in the gas phase
Journal:   Trans. Faraday Soc.
Volume:   56
Page(s):   1296 - 1303
Year:   1960
Reference type:   Journal article
Squib:   1960KIR/KNO1296-1303

Reaction:   (CH3)2CHOOH·OH + (CH3)2CHO·
Reaction order:   1
Temperature:   553 - 653 K
Rate expression:   1.58x1015 [s-1] e-167121 [±3351 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Benzene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
553 2.59E-1
575 1.04E0
600 4.46E0
625 1.71E1
650 5.87E1
653 6.77E1