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Author(s):   Butler, E.T.; Polanyi, M.
Title:   Rates of pyrolysis and bond energies of substituted organic iodides (Part I)
Journal:   Trans. Faraday Soc.
Volume:   39
Page(s):   19 - 36
Year:   1943
Reference type:   Journal article
Squib:   1943BUT/POL19-36

Reaction:   CH3COCH2ICH3C(O)CH2(·) + I
Reaction order:   1
Temperature:   703 - 767 K
Pressure:  6.88E-3 - 1.03E-2 bar
Rate expression:   1.0x1013 [s-1] e-187907 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
703 1.09E-1
725 2.90E-1
750 8.19E-1
767 1.60E0