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Author(s):   Nesbitt, D.J.; Leone, S.R.
Title:   Laser-initiated Cl2/hydrocarbon chain reactions: Time-resolved infrared emission spectra of product vibrational excitation
Journal:   J. Phys. Chem.
Volume:   86
Year:   1982
Reference type:   Journal article
Squib:   1982NES/LEO4962

Reaction:   sec-C4H9 + Cl2sec-C4H9Cl + ·Cl
Reaction order:   2
Reference reaction:   1-C4H10 + ·Cl → Other Products + HCl
Temperature:   298 K
Pressure:  1.67 bar
Rate expression:   6.79x10-12 [±1.49x10-12 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Other (IR)

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