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Author(s):   Tyndall, G.S.; Orlando, J.J.; Wallington, T.J.; Dill, M.; Kaiser, E.W.
Title:   Kinetics and mechanisms of the reactions of chlorine atoms with ethane, propane, and n-butane
Journal:   Int. J. Chem. Kinet.
Volume:   29
Page(s):   43 - 55
Year:   1997
Reference type:   Journal article
Squib:   1997TYN/ORL43-55

Reaction:   sec-C4H9 + Cl2sec-C4H9Cl + ·Cl
Reaction order:   2
Reference reaction:   sec-C4H9 + O2 → C2H5CH(CH3)O2
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.13 - 0.80 bar
Rate expression:   2.8±1.1x10-1
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

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