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Title: The thermal decomposition of trans-1,2-dimethylcyclobutane
Journal: J. Am. Chem. Soc.
Volume: 83
Page(s): 4884 - 4888
Year: 1961
Reference type: Journal article
Squib: 1961GER/WAL4884-4888
Reaction:
Cyclobutane, 1,2-dimethyl-, trans- → C2H4 + CH3CH=CHCH3
Reaction order:
1
Temperature:
663 - 713
K
Pressure: 1.73E-2 - 0.50 bar
Rate expression:
2.9x1015 [s-1] e-265232 [J/mole]/RT
Bath gas:
Cyclobutane, 1,2-dimethyl-, trans-
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 663 | 3.69E-6 |
| 675 | 8.67E-6 |
| 700 | 4.69E-5 |
| 713 | 1.08E-4 |