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Author(s):   Hidaka, Y.; Higashihara, T.; Ninomiya, N.; Oki, T.; Kawano, H.
Title:   Thermal isomerization and decomposition of 1,2-butadiene in shock waves
Journal:   Int. J. Chem. Kinet.
Volume:   27
Page(s):   331 - 341
Year:   1995
Reference type:   Journal article
Squib:   1995HID/HIG331-341

Reaction:   1,2-butadiene1,3-Butadiene
Reaction order:   1
Temperature:   1100 - 1600 K
Pressure:  1.25 - 2.33 bar
Rate expression:   2.5x1013 [s-1] e-263569 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 7.63E0
1150 2.67E1
1200 8.42E1
1250 2.42E2
1300 6.42E2
1350 1.59E3
1400 3.67E3
1450 8.01E3
1500 1.66E4
1550 3.28E4
1600 6.22E4