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Author(s):   Peeters, J.; Boullart, W.; Devriendt, K.
Title:   CH(a4Σ- and/or X2II) formation in the reaction between ketenyl radicals and oxygen atoms. Determination of the CH yield between 405 and 960 K
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   3583 - 3591
Year:   1995
Reference type:   Journal article
Squib:   1995PEE/BOU3583-3591

Reaction:   + HCCOCO2 + ·CH
Reaction order:   2
Reference reaction:   + HCCO → Products
Reference reaction order:   2
Temperature:   450 - 960 K
Pressure:  2.03 bar
Rate expression:   2.5x10-1 e-3642 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
450 9.45E-2
500 1.04E-1
550 1.13E-1
600 1.20E-1
650 1.27E-1
700 1.34E-1
750 1.39E-1
800 1.45E-1
850 1.49E-1
900 1.54E-1
950 1.58E-1
960 1.58E-1