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Accessibility information
Author(s):   Huybrechts, G.; Meyers, L.; Verbeke, G.
Title:   Stability and reactions of the tetrachloroethyl radical
Journal:   Trans. Faraday Soc.
Volume:   58
Year:   1962
Reference type:   Journal article
Squib:   1962HUY/MEY1128

Reaction:   CHCl2CCl3 + ·ClCl2 + CCl3CHCl
Reaction order:   2
Temperature:   433 - 497 K
Pressure:  8.00E-2 - 0.15 bar
Rate expression:   1.05x10-10 [cm3/molecule s] e-74913 [J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   Cl2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
433 9.62E-20
450 2.11E-19
475 6.06E-19
497 1.40E-18