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Title: Kinetic Study of the Reactions of CF3O2 Radicals with Cl and NO
Journal: Phys. Chem. Chem. Phys.
Volume: 1
Page(s): 5087 - 5096
Year: 1999
Reference type: Journal article
Squib: 1999FLO/BUR5087-5096
Reaction:
CF3O2 + ·Cl → ClO + CF3O
Reaction order:
2
Temperature:
298
K
Pressure: 9.33E-4 - 4.00E-3 bar
Rate expression:
4.2x10-11 [±8.0x10-12 cm3/molecule s]
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Electron beam
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
Comments:
F from microwave discharge of F2/HeCF3 from CHF3 + HCF3O2 from CF3 + O2Detected CF3O2 with mass spec
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