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Author(s):   Geiger, H.; Wiesen, P.; Becker, K.H.
Title:   A Product Study of the Reaction of CH Radicals with Nitric Oxide at 298 K
Journal:   Phys. Chem. Chem. Phys.
Volume:   1
Page(s):   5601 - 5606
Year:   1999
Reference type:   Journal article
Squib:   1999GEI/WIE5601-5606

Reaction:   ·CH + NO + NCO
Reaction order:   2
Temperature:   289 K
Pressure:  0.13 bar
Rate expression:   4.4x10-11 [±5.0x10-11 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Very low pressure cells (VLPP,Knudsen)
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Multiphoton dissociation of CHClBr2 source of CH.Reaction monitored by formation of NCO.Rate constant is for overall reaction.Slow rate constant suggests the reaction is complex, possibly involving the formation of an intermediate.

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