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Author(s):   Wallington, T.J.;Hurley, M.D.;Haryanto, A.
Title:   Kinetics of the gas phase reactions of chlorine atoms with a series of formates
Journal:   Chem. Phys. Lett.
Volume:   432
Page(s):   57 - 61
Year:   2006
Reference type:   Journal article
Squib:   2006WAL/HUR57-61

Reaction:   HCOO(CH2)3CH3 + ·Cl → Products
Reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   1.12x10-10 [±1.4x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   The rate constant was measured relative reaction Cl+C2H2 and Cl+C2H4

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