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Author(s):   Chu, L.K.; Lee, Y.P.
Title:   Infrared absorption of gaseous c-ClCOOH and t-ClCOOH recorded with a step-scan Fourier-transform spectrometer
Journal:   J. Chem. Phys.
Volume:   130
Year:   2009
Reference type:   Journal article
Squib:   2009CHU/LEE174304

Reaction:   HCOOH + ·ClHOC(·)O + HCl
Reaction order:   2
Temperature:   363 - 363 K
Pressure:  7.24E-2 bar
Rate expression:   1.8x10-13 [±5.0x10-14 cm3/molecule s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

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