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Author(s):   Galiba, I.; Tedder, J.M.; Watson, R.A.
Title:   Free-radical substitution in aliphatic compounds. Part V. The halogenation of 1,1,1-trifluoropentane
Journal:   J. Chem. Soc. A
Year:   1964
Reference type:   Journal article
Squib:   1964GAL/TED1321

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1964GAL/TED1321   1-C4H10 + Br·sec-C4H9 + HBr  298 - 503   6.61E-11       4.27E04   2.21E-18  2
  1964GAL/TED1321   1-C4H10 + Br·1-C4H9 + HBr  298 - 503   2.09E-11       5.60E04   3.15E-21  2
  1964GAL/TED1321   1-C4H10 + ·Clsec-C4H9 + HCl  298 - 503   3.32E-11       1247   2.01E-11  2
  1964GAL/TED1321   1-C4H10 + ·Cl1-C4H9 + HCl  298 - 503   2.62E-11       3342   6.81E-12  2
  1964GAL/TED1321   Pentane, 1,1,1-trifluoro- + Br·HBr + CF3(CH2)3CH2  313 - 503   2.09E-11       5.44E04      2
  1964GAL/TED1321   Pentane, 1,1,1-trifluoro- + ·ClHCl + CF3(CH2)3CH2  273 - 503   1.05E-11       2087   4.51E-12  2

Search returned 6 records.