Author(s):   Wallington, T.J.; Hurley, M.D.; Shi, J.; Maricq, M.M.; Sehested, J.; Nielsen, O.J.; Ellermann, T.
Title:   A kinetic study of the reaction of fluorine atoms with CH₃F, CH₃Cl, CH₃Br, CF₂H₂, CO, CF₃H, CF₃CHCl₂, CF₃CH₂F, CHF₂CHF₂, CF₂ClCH₃, CHF₂CH₃, and CF₃CF₂H at 295 ± 2 K
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   651 - 665
Year:   1993
Reference type:   Journal article
Squib:   1993WAL/HUR651-665

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |

Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
1993WAL/HUR651-665	CH₃Br + ·F → Products	295	3.01E-11		2
1993WAL/HUR651-665	CH₃Br + ·F → Products	295	0.44		2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1993WAL/HUR651-665	CH₃Cl + ·F → Products	295	3.30E-11		2
1993WAL/HUR651-665	CH₃Cl + ·F → Products	295	0.48		2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1993WAL/HUR651-665	CH₂F₂ + ·F → ·CHF₂ + HF	295	4.30E-12		2
1993WAL/HUR651-665	CH₂F₂ + ·F → ·CHF₂ + HF	295	0.06		2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1993WAL/HUR651-665	CH₃CHF₂ + ·F → Other Products + HF	295	1.69E-11		2
1993WAL/HUR651-665	CH₃CHF₂ + ·F → Other Products + HF	295	0.25		2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1993WAL/HUR651-665	CHF₃ + ·F → ·CF₃ + HF	295	1.40E-13		2
1993WAL/HUR651-665	CHF₃ + ·F → ·CF₃ + HF	295	2.00E-03		2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1993WAL/HUR651-665	CH₃CF₂Cl + ·F → Products	295	3.90E-12		2
1993WAL/HUR651-665	CH₃CF₂Cl + ·F → Products	295	0.06		2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1993WAL/HUR651-665	CF₃CHCl₂ + ·F → HF + CF₃CCl₂	295	1.20E-12		2
1993WAL/HUR651-665	C₂F₅H + ·F → C₂F₅ + HF	295	3.50E-13		2
1993WAL/HUR651-665	C₂F₅H + ·F → C₂F₅ + HF	295	5.20E-03		2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1993WAL/HUR651-665	CHF₂CHF₂ + ·F → HF + CHF₂CF₂	295	1.00E-12		2
1993WAL/HUR651-665	CHF₂CHF₂ + ·F → HF + CHF₂CF₂	295	0.01		2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1993WAL/HUR651-665	CH₃F + ·F → Products	295	3.70E-11		2
1993WAL/HUR651-665	CH₃F + ·F → Products	295	0.54		2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1993WAL/HUR651-665	CO + ·F → FCO	295	5.50E-13		2
1993WAL/HUR651-665	CF₃CH₂F + ·F → HF + CF₃CHF	295	1.30E-12		2
1993WAL/HUR651-665	CF₃CH₂F + ·F → HF + CF₃CHF	295	0.02		2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2

Search returned 22 records.