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Accessibility information
Author(s):   Knox, J.H.; Nelson, R.L.
Title:   Competitive chlorination reactions in the gas phase: hydrogen and C1-C5 saturated hydrocarbons
Journal:   Trans. Faraday Soc.
Volume:   55
Year:   1959
Reference type:   Journal article
Squib:   1959KNO/NEL937

Reaction:   1-C4H10 + ·Cl1-C4H9 + HCl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Reference reaction order:   2
Temperature:   193 - 593 K
Pressure:  0.67 bar
Rate expression:   8.89x10-1±3.6x10-2 e1048 [±126 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
193 1.71E0
200 1.67E0
225 1.56E0
250 1.47E0
275 1.41E0
300 1.35E0
325 1.31E0
350 1.27E0
375 1.24E0
400 1.22E0
425 1.20E0
450 1.18E0
475 1.16E0
500 1.14E0
525 1.13E0
550 1.12E0
575 1.11E0
593 1.10E0