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Author(s):   Qian, H.-B.; Turton, D.; Seakins, P.W.; Pilling, M.J.
Title:   A Laser Flash Photolysis/IR Diode Laser Absorption Study of the Reaction of Chlorine Atoms with Selected Alkanes
Journal:   Int J. Chem. Kinet.
Volume:   34
Page(s):   86 - 94
Year:   2002
Reference type:   Journal article
Squib:   2002QIA/TUR86-94

Reaction:   1-C4H10 + ·Cl1-C4H9 + HCl
Reaction order:   2
Temperature:   298 K
Rate expression:   1.91x10-10 [±1.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption
Comments:   Cl from oxalyl chloride photolysis at 193 nm, IR diode laser absorption (HCl product), Herriot cell, structure activity relationship (SAR) for Cl atom abstraction reactions given, this work obtained k = 1.91(+/-0.10)E-10, but the authors recommend 2.06(+/-0.12)E-10 based on three studies

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