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Title: Atmospheric chemistry of pivalaldehyde and isobutyraldehyde: Kinetics and mechanisms of reactions with Cl atoms, fate of (CH3)3CC(O) and (CH3)2CHC(O) radicals, and self-reaction kinetics of (CH3)3CC(O)O2 and (CH3)2CHC(O)O2 radicals
Journal: J. Phys. Chem. A
Volume: 108
Page(s): 795 - 805
Year: 2004
Reference type: Journal article
Squib: 2004LEC/VIL795-805
Reaction:
tert-C4H9Cl + ·Cl → Products
Reaction order:
2
Reference reaction:
C2H5Cl + ·Cl → Products
Reference reaction order:
2
Temperature:
296
K
Pressure: 7.00E-3 bar
Rate expression:
1.23x10-11±1.4x10-12
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
Comments:
Reference rate constant is (8.05 ± 0.57) x 10-12 CM3 s-1
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