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Title: Hydrogen-atom-induced decomposition of trichloroethylene at high temperatures
Journal: J. Phys. Chem.
Volume: 99
Page(s): 3156 - 3161
Year: 1995
Reference type: Journal article
Squib: 1995TSA/WAL3156-3161
Reaction:
C2HCl3 + H· → CH2=CCl2 + ·Cl
Reaction order:
2
Temperature:
300 - 1140
K
Rate expression:
1.1x10-11 [cm3/molecule s] (T/298 K)0.97 e-11723 [J/mole]/RT
Bath gas:
Ar
Category: Review
Data type:
Experimental value and limited review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 300 | 1.00E-13 |
| 350 | 2.28E-13 |
| 400 | 4.30E-13 |
| 450 | 7.13E-13 |
| 500 | 1.08E-12 |
| 550 | 1.53E-12 |
| 600 | 2.06E-12 |
| 650 | 2.67E-12 |
| 700 | 3.35E-12 |
| 750 | 4.10E-12 |
| 800 | 4.91E-12 |
| 850 | 5.78E-12 |
| 900 | 6.69E-12 |
| 950 | 7.66E-12 |
| 1000 | 8.67E-12 |
| 1050 | 9.72E-12 |
| 1100 | 1.08E-11 |
| 1140 | 1.17E-11 |