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Author(s):   Tsang, W.; Walker, J.A.
Title:   Hydrogen-atom-induced decomposition of trichloroethylene at high temperatures
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   3156 - 3161
Year:   1995
Reference type:   Journal article
Squib:   1995TSA/WAL3156-3161

Reaction:   C2HCl3 + CH2=CCl2 + ·Cl
Reaction order:   2
Reference reaction:   1,3,5-Trimethylbenzene + 1,3-Dimethylbenzene + ·CH3
Temperature:   970 - 1140 K
Rate expression:   9.96x10-11 [cm3/molecule s] e-20287 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
970 8.05E-12
975 8.16E-12
1000 8.68E-12
1025 9.22E-12
1050 9.75E-12
1075 1.03E-11
1100 1.08E-11
1125 1.14E-11
1140 1.17E-11